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The capacity of a lithium-ion battery decreases during cycling. This capacity loss or fade occurs due to several different mechanisms associated with unwanted side reactions that occur in these batteries. The same reactions occur during overcharge and cause electrolyte decomposition, passive film formation, active material dissolution, and other phenomena. As the battery ages the accuracy of state of charge prediction decreases and vulnerability to persistent overcharge increases. Moreover, as the battery ages, its tolerance to such unintended overcharge changes. This tolerance depends on the nature of the history of cycle and calendar aging. A map of this tolerance in the BMS can provide awareness of the factor of safety due to overcharge as battery ages. Signatures of early warning signs of incipient thermal runaway due to overcharge can also be very useful features in a BMS.

This paper reports on the third part of a continued study (SAE Papers 961182, 971636) to develop the Ignition Quality Tester (IQT™). Past research has shown that this automated laboratory/refinery apparatus can be used to accurately predict the cetane number of middle distillates and alternative fuels using small sample volumes (< 50 mL). The paper reports on the main objective of a study performed by Advanced Engine Technology Ltd. (AET), in co-operation with its research partners. The primary research objective of this work is to further the understanding of fuel preparation (fuel air mixing) and start of combustion processes in the IQT™. Key to this understanding is the manner in which single molecule compounds and full boiling-range diesel fuels behave during these processes. Insights are provided into the manner in which the American Society for Testing and Materials (ASTM) D-613 primary reference fuels (PRFs) undergo fuel preparation and start of combustion in the IQT™.

An investigation was performed to determine the effects of applying on-highway heavy-duty diesel engine emissions reduction technology to an off-highway version of the engine. Special attention was paid to the typical constraints of fuel consumption, heat rejection, packaging and cost-effectiveness. The primary focus of the effort was NOx, reduction while hopefully not worsening other gaseous and particulate emissions. Hardware changes were limited to “bolt-on” items, thus excluding piston and combustion chamber modifications. In the final configuration, NOx was improved by 28 percent, particulates by 58 percent, CO and HC were also better and the fuel economy penalty was limited to under 4 percent. Observations are made about the effectiveness of various individual and combined strategies, and potential problems are identified.

Recent legislation, including the California Clean Air Act of 1988 and the Federal Clean Air Act Amendment of 1990, includes off-road engines, equipment, and vehicles as targets for new exhaust emissions regulations. The Santa Barbara County Air Pollution Control District in cooperation with EXXON USA is conducting a major Low NOx Demonstration Program including mobile sources, construction equipment, and offshore equipment. As a part of this program, an existing backhoe has been retrofitted with a low NOx engine and demonstrated in the field. This paper discusses the work performed to allow Case model 580 backhoes to be retrofitted with Cummins 4BTAA3.9 on-highway turbocharged diesel engines. A standard production conversion kit can be used to mount the new engines in place of the older existing JI Case engines in some models while other newer models already have 4B3.9 engines. In addition, an air-to-air aftercooler and associated plumbing was designed and installed.

This paper describes the development of a CVS compatible sampling system for automotive sulfate emissions. The design resulted from a consensus of ideas from EPA and industry. The system can be used with either a positive displacement pump or critical flow venturi CVS. A mist generator was developed to quantitatively inject sulfuric acid into the tunnel. While sulfate losses were acceptable using the mist generator, with actual automotive exhaust sulfate losses were much higher. The reasons for these losses were investigated. Sulfate losses in the tubing between the car and sulfate tunnel were also investigated.

As part of the U.S. Environmental Protection Agency’s (EPA’s) continuing assessment of advanced light-duty automotive technologies in support of regulatory and compliance programs, a 2018 Toyota Camry A25A-FKS 4-cylinder, 2.5-liter, naturally aspirated, Atkinson Cycle engine with cooled exhaust gas recirculation (cEGR) was benchmarked. The engine was tested on an engine dynamometer with and without its 8-speed automatic transmission, and with the engine wiring harness tethered to a complete vehicle parked outside of the test cell. Engine and transmission torque, fuel flow, key engine temperatures and pressures, onboard diagnostics (OBD) data, and Controller Area Network (CAN) bus data were recorded. This paper documents the test results under idle, low, medium, and high load engine operation. Motoring torque, wide open throttle (WOT) torque and fuel consumption are measured during transient operation using both EPA Tier 2 and Tier 3 test fuels.

Four high-efficiency alternative combustion modes were modeled to determine the potential brake thermal efficiency (BTE) relative to a traditional lean burn compression ignition diesel engine with selective catalytic reduction (SCR) aftertreatment. The four combustion modes include stoichiometric pilot-ignited gasoline with EGR dilution (SwRI HEDGE technology), dual fuel premixed compression ignition (University of Wisconsin), gasoline partially premixed combustion (Lund University), and homogenous charge compression ignition (HCCI) (SwRI Clean Diesel IV). For each of the alternative combustion modes, zero-D simulation of the peak torque condition was used to show the expected BTE. For all alternative combustion modes, simulation showed that the BTE was very dependent on dilution levels, whether air or EGR. While the gross indicated thermal efficiency (ITE) could be shown to improve as the dilution was increased, the required pumping work decreased the BTE at EGR rates above 40%.

It is widely acknowledged that the CFR octane rating engines are not representative of modern engines and that there is a gap in the quantification of knock severity between the two engine types. As part of a comprehensive study of the autoignition of different fuels in both the CFR octane rating engines and a modern, direct injection, turbocharged spark-ignited engine, a series of fuel blends were tested with varying composition, octane numbers and ethanol blend levels. The paper reports on the fourth part of this study where cylinder pressures were recorded under standard knock conditions in CFR engines under RON and MON conditions using the ASTM prescribed instrumentation. By the appropriate signal conditioning of the D1 detonation pickups on the CFR engines, a quantification of the knock severity was possible that had the same frequency response as a cylinder pressure transducer.

Nitrous Oxide (N₂O) is a greenhouse gas with a Global Warming Potential (GWP) of 298-310 (298-310 times more potent than carbon dioxide (CO₂)). As a result, any aftertreatment system that generates N₂O must be well understood to be used effectively. Under low temperature conditions, N₂O can be produced by Selective Catalytic Reduction (SCR) catalysts. The chemistry is reasonably well understood with N₂O formed by the thermal decomposition of ammonium nitrate. Ammonium nitrate and N₂O form in oxides of nitrogen (NOx) gas mixtures that are high in nitrogen dioxide (NO₂). This mechanism occurs at a relatively low temperature of about 200°C, and can be controlled by maintaining the nitric oxide (NO)/NO₂ ratio above 1. However, N₂O has also been observed at relatively high temperatures, in the region of 500°C.

Nitrous Oxide (N2O) is a greenhouse gas with a Global Warming Potential (GWP) of 298-310 [1,2] (298-310 times more potent than carbon dioxide (CO2)). As a result, any aftertreatment system that generates N2O must be well understood to be used effectively. Under low temperature conditions, N2O can be produced by Selective Catalytic Reduction (SCR) catalysts. The chemistry is reasonably well understood with N2O formed by the thermal decomposition of ammonium nitrate [3]. Ammonium nitrate and N2O form in oxides of nitrogen (NOx) gas mixtures that are high in nitrogen dioxide (NO2)[4]. This mechanism occurs at a relatively low temperature of about 200°C, and can be controlled by maintaining the nitric oxide (NO)/NO2 ratio above 1. However, N2O has also been observed at relatively high temperatures, in the region of 500°C.

Despite considerable progress over the last several decades, California continues to face some of the most significant air quality problems in the United States. These continued issues highlight the need for further mobile source NOX reductions to help California and other areas meet ambient air quality targets mandated by the U.S. EPA. Beginning in 2014, the California Air Resources Board (CARB) launched a program aimed at demonstrating technologies that could enable heavy-duty on-highway engines to reach tailpipe NOX levels up to 90% below the current standards, which were implemented in 2010. At the same time, mandated improvements to greenhouse gas emissions (GHG) require that these NOX reductions be achieved without sacrificing fuel consumption and increasing GHG emissions.

With the conclusion of the California Air Resources Board (CARB) Stage 1 Ultra-Low NOX (ULN) program, there continues to be a commitment for identifying potential pathways to demonstrate 0.02 g/bhp-hr NOX emissions. The Stage 1 program focused on achieving the ULN levels on the heavy-duty regulatory cycles utilizing a turbo-compound engine which required the integration of novel catalyst technologies and a supplemental heat source. While the aftertreatment configuration provided a potential solution to meet the ULN target, a complicated approach with a greenhouse gas (GHG) penalty was required to overcome challenges from low temperature exhaust. A subsequent Stage 2 program was concerned with the development of a new low load test cycle and evaluating the trade-off between GHG and tailpipe NOX on the Stage 1 ULN solution.

Life prediction and reliability analysis of a cam roller system were investigated. From the tribological analysis, the cam roller system was found to operate under low film parameter conditions and components were subjected to the risk of contact fatigue. Surface analysis performed on the failed rollers indicated that the surface distress was the primary cause for failure. Then, numerical analyses were performed to evaluate the cam roller life and its related reliability. The adopted approach combined a contact fatigue crack growth calculations with a probabilistic model for controlling the design uncertainty. The computation-efficient Fast Probabilistic Integration (FPI™) code was used to solve the problem. With appropriate descriptions for uncertainty distributions, the surface fatigue life of the specified cam roller system can be predicted along with a confident reliability level.

Automotive catalytic converters must provide a very high level of mechanical and thermal durability to maintain performance during their 100,000 to 150,000 mile life expectancy. The work reported herein characterizes the converter as a base (can) excited spring (mat material) supported mass (substrate). A mat material coupon test apparatus was developed for the purpose of providing parameter data for the converter model in the form of stiffness and material loss factor data as a function of shear deflection across the mat. An intumescent mat material was chosen and its dynamic properties evaluated for a range of converter operating parameters. The mat material response properties were placed into a mat material database as a function of gap bulk density, substrate temperature, and temperature gradient across the mat.

To aid in the catalytic converter design and development process, a test apparatus was designed and built which will allow comparative evaluation of the durability of candidate mat materials under highly controlled thermal and vibration environments. The apparatus directly controls relative shear deflection between the substrate and can to impose known levels of mat material strain while recording the transmitted shear force across the mat material. Substrate and can temperatures are controlled at constant levels using a resistive thermal exposure (RTE) technique. Mat material fatigue after several million cycles is evident by a substantial decrease in the transmitted force. A fragility test was found to be an excellent method to quickly compare candidate materials to be used for a specific application. Examples of test results from several materials are given to show the utility of the mat material evaluation technique.

An increasing number of passenger vehicle exhaust systems incorporate catalytic converters that are “close-coupled” to the exhaust manifold to further reduce the quantity of cold-start emissions and increase overall catalyst conversion efficiencies. In general, close-coupled catalytic converters are not necessarily subjected to higher inlet exhaust temperatures than conventional underbody catalytic converters. To establish a foundation of on-vehicle temperature data, several passenger vehicles with close-coupled catalytic converters were studied while operating on a chassis dynamometer. Converter temperatures were measured over a variety of vehicle test conditions, including accelerations and extended steady-state speeds for several throttle positions, at both zero- and four-percent simulated road grades.

In order to further reduce vehicle cold-start emissions, the use of catalytic converters that are “close-coupled” to the exhaust manifold is increasing. To understand the vibrational environment of close-coupled and underbody converters, a laboratory study was conducted on several passenger vehicles. Catalytic converter vibration spectra were measured on a chassis dynamometer with the vehicle operating over a variety of test conditions. Vehicle operating conditions included hard accelerations and extended steady-state speeds at distinct throttle positions over zero-percent and four-percent simulated road grades.

To counter the adverse impact on the formation of harmful unregulated emissions such as nitro-polycyclic aromatic hydrocarbons (NPAH), catalyst companies and researchers have been developing catalytic coatings that have the capability of suppressing the formation of NO2. NO2 is formed at low exhaust temperatures with potentially greater concentrations at part load engine operation. Haldor Topsoe, a catalyst company from Denmark, developed such a catalytic coating for DPFs. A sample was provided to Southwest Research Institute (SwRI) to conduct this research with a view of potentially improving NO2-suppressing formulations in the future. The Haldor Topsoe diesel particulate filter (DPF) with its novel coating was tested together with three other DPFs and the results confirmed the capability of this DPF to suppress the formation of NO2. This characteristic was apparent in all five engine test modes selected to cover the full engine operating range.

Stringent emissions regulations and the need for lower tailpipe emissions are pushing the development of low-carbon alternative fuels. H2 is a zero-carbon fuel that has the potential to lower CO2 emissions from internal combustion engines (ICEs) significantly. Moreover, this fuel can be readily implemented in ICEs with minor modifications. Batteries can be argued to be a good zero tailpipe emission solution for the light-duty sector; however, medium and heavy-duty sectors are also in need of rapid decarbonization. Current strategies for H2 ICEs include modification of the existing spark ignition (SI) engines to run on port fuel injection (PFI) systems with minimal changes from the current compressed natural gas (CNG) engines. This H2 ICE strategy is limited by knock and pre-ignition. One solution is to run very lean (lambda >2), but this results in excessive boosting requirements and may result in high NOx under transient conditions.

An electromagnetic valve actuation (EVA) system was developed and applied to a Kohler Command Series engine. Engine development and testing was conducted for the purpose of evaluating the performance of the EVA-equipped engine, running on natural gas, in an engine-test laboratory environment. As part of this effort, a personal computer-based engine control system, which managed the fueling, ignition, throttling, and intake/exhaust valve control functions, was developed. The evaluation included an investigation into increasing engine power output and full load efficiency, as well as increased part load efficiency. Techniques including optimized valve events as a function of operating condition, and throttleless operation using early and late intake valve closing are presented. Engine simulation results are compared with actual engine data and presented in this paper.